Pre-concentration and Determination of Low-traces of Copper Ions in Different Mediums Using Dispersive Liquid-liquid Micro-extraction (DLLME)

نویسندگان

  • Davood Kaviani Young Researchers and Elite Club, East Tehran Branch, Islamic Azad University, Tehran, Iran
  • Majid Saghi Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran
  • Mohammad Hossein Bigtan Department of chemistry, Arak branch, Islamic Azad University, Arak, Iran
چکیده مقاله:

In the paper, in order to pre-concentrate and measure the low values of Cu ions, the new, simple,quick and very sensitive method of Dispersed Liquid-Liquid Micro Extraction (DLLME) coupledwith flame Atomic Absorption spectrometry (AA) has been utilized. The DLLME techniquecoupled with AA )AA-DLLME) was run inside one narrow tube which constitute aqueous samples.In this method, a mixture of toluene and methanol 90:10 (v/v) was injected into the aqueous sampleas extractor and disperser agent and then Cu and diethyldithiocarbamate (DDTC) complex wasconcentrated inside the toluene and was collected on the sample solution. In order to optimize thefactors affecting on the process, different parameters affected on the Cu extraction such as kind andvolume of extractor, volume of dispersing solvent, pH of sample solution, ligand concentration,time for bubble formation and salt effect were studied. Under optimal condition, limit of detection(LOD), relative standard deviation (RSD) and limit of linearity (LOL) for calibration curve weremeasured and were obtained as: 1.2 μg.l-1, 3.64% and 0.01-1 mg.l-1, respectively. This method wassuccessfully applied to determine Cu in environmental waters, milk powder, liquid milk and orangejuice.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A Dispersive Liquid–Liquid Micro–Extraction Technique for the Pre–concentration and Quantification of Vitamin D3 in Milk and Yogurt Samples Using a Non-Aqueous HPLC Method

In present study, a DLLME-HPLC-UV method was developed and validated for the extraction, pre–concentration, and subsequently quantification of vitamin D3 (Vit D3) in milk and yogurt samples. In order to be able to extract Vit D3 from studied samples efficiently, the DLLME procedure was optimized with respect to the parameters affecting the extraction efficacy, w...

متن کامل

A Dispersive Liquid–Liquid Micro–Extraction Technique for the Pre–concentration and Quantification of Vitamin D3 in Milk and Yogurt Samples Using a Non-Aqueous HPLC Method

In present study, a DLLME-HPLC-UV method was developed and validated for the extraction, pre–concentration, and subsequently quantification of vitamin D3 (Vit D3) in milk and yogurt samples. In order to be able to extract Vit D3 from studied samples efficiently, the DLLME procedure was optimized with respect to the parameters affecting the extraction efficacy, w...

متن کامل

Determination of Amphetamine and Methamphetamine by Dispersive Liquid Phase Micro-extraction: A Novel Experimental Approach

Background: A syringe to syringe dispersive liquid phase micro-extraction-floating organic drop was applied and used for the simultaneous extraction and pre-concentration of trace amounts of amphetamine (AMP) and methamphetamine (MAMP) in urine samples. The extracted analytes were determined by high performance liquid chromatography along with diode array detection. Materials & Methods: In thi...

متن کامل

Evaluation of thallium rate in soil after dispersive liquid-liquid micro-extraction

Thallium is widely found in nature, but the only inorganic stones full of this element are crookesite and lorandit. It isalso found in pyrites of copper, lead and inorganic stones. The element and its compositions are toxic and harmful to theenvironment; therefore, its application requires caution and further research. It is important to develop sensitive andaccurate analytical methods to deter...

متن کامل

Application of Microfunnel Magnetic Stirring Assisted Liquid-Liquid Micro-extraction Method for Pre-concentration and Determination of Silver Ion in Water Samples

In this research, a highly sensitive, selective, rapid and simple micro-funnel magnetic stirringassisted liquid–liquid microextraction (MF-MSA-LLME) method combined with flame atomic absorption spectrometry (FAAS) was introduced for the preconcentration, extraction, and measurement of trace amounts of silver ion. In this method 1-(2–Pyridylazo)-2-naphthol (PAN) and 1-octanol were used as chelat...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 12  شماره 4

صفحات  51- 65

تاریخ انتشار 2018-12-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023